4. Measurement
Before starting any measurement, make sure the RAD7 memory and run
number are not full. (Data, Free [ENTER]) and read the number of
free cycles
- should be more than 100, (Data, Read [ENTER]) and see the run number
of the last run - should be less than 90. If the space or available
run numbers are too few, download the data from the RAD7 to a PC
and erase the RAD7 memory (Data, Erase, Yes [ENTER]).
There are three modes of measurement. One is by grab sample, another
by continous monitoring in standard protocol and the third in THORON
mode, with the pump running continuously.
4.1 For GRAB protocol, it is necessary first to purge the RAD7 for
ten minutes or more with dry, fresh air, before connecting the
probe.
With the probe disconnected but the drying unit hooked up to the
RAD7 start purging (Test, Purge, [ENTER]). After at least five
minutes push ‘Menu’ (to
stop the purge’. With the printer switched off, put the RAD7 in
SNIFF protocol (Setup, Protocol, Sniff [ENTER]) and start a reading (Test,
Start). Go to the third status window (Menu, Enter, Enter, Rt. Arrow,
Rt. Arrow) and observe the relative humidity in the top righthand corner.
Let the RAD7 continue sniffing until the relative humidity drops below
6%.
If the RAD7 was previously used to measure a high radon concentration,
it would be prudent also to measure the count rate in window
A while the Sniff reading was continuing. Go to the fifth status
window (from
the third, just Rt. Arrow, Rt. Arrow). The lefthand number
is the
count rate. Typically, 0.25 cpm would be equivalent to a radon
concentration of 1 pCi/L, or about 40 Bq/m3. Soil gas is seldom
less than 100 pCi/L,
so if the count rate in window A has dropped to below 0.5 cpm
and the
humidity to below 6%, the RAD7 is ready to make the next GRAB
protocol reading.
Set the protocol to “Grab” (Setup, Protocol, Grab [ENTER])
then turn off the RAD7. Connect the tubing to the probe. Switch on the
printer, switch on the RAD7 and let the printer print out a header for
this measurement. Check the header to make sure the setup is what is
required. Go to Test Start and push [ENTER] to start the measurement.
The RAD7 pump will run for five minutes. The instrument will wait another
five minutes and then count for four five-minute cycles. At the end of
the half-hour period, the RAD7 will print out a summary of the measurement,
including an average radon concentration in the soil gas from the four
5-minute cycle measurements. This method gives a quick (half-hour) reading
and uses the least amount of soil gas. The accuracy will depend on the
radon concentration, and would typically be better than +/- 10%.
If necessary, the soil gas sample can be pumped out of the ground by
a sampling pump, and fed to a Tedlar sample bag for later analysis
by the RAD7. With that methodology, care should be taken to ensure
that
the sample is truly soil gas from the sampling point, and that there
is at least 5 litres of soil gas sample in the bag. When analysis is
made later, at the RAD7, care should be taken that it is first purged
thoroughly, so that the relative humidity inside the instrument drops
below 6%. Then the bag is connected to the drying unit and a grab sample
protocol measurement started. The result should be corrected for the
decay of radon in the sample during the period from acquisition to
analysis.
4.2 Continuous monitoring is a simpler method of measuring the soil
gas radon concentration and provides time resolution in the event
that the
weather is changing. The setup is as above, but the RAD7 preset protocol
should be set to 1-day. It is still desirable to purge the RAD7 before
starting the measurement, but the continuous monitoring process will
itself serve to purge the instrument and dry it out after a while.
In this protocol, the RAD7 will pump for the first five minutes of
every
half-hour cycle, and then for only one minute in every five, once
the relative humidity drops below 10%. There will be a reading after
every
half-hour cycle, though the first reading will be low because the
218-Po decay rate in the detector takes more than 10 minutes to reach
equilibrium
with the radon concentration in the measurement chamber. So there
will be a reading printed out (and stored in the RAD7 memory) every
half
hour. The accuracy of readings will be +/-5% for the typical high
radon concentrations
found in soil gas. This method will draw from the sampling point
a volume of soil gas equal to the flow rate of the pump (L/min) times
10 minutes,
in every half-hour cycle. In a typical, porous soil, the pump flow
rate may be around 0.5 L/min. So the soil gas extraction rate will
be around
10 litres per hour. After two hours of continuous monitoring, this
would amount to 20 L, which would come from a sphere around the sampling
point
of around 6" (15 cm) radius. Less porous soils would have a slower
flow rate, so the volume of soil gas sampled would be less.
4.3 Thoron protocol uses 5-minute cycles and prints out both the
radon and thoron concentrations at the end of every cycle. However,
thoron
has a short half-life (one minute) so that the pump has to run
continuously. The first two cycles should be ignored, while the radon
reading equilibrates.
Thereafter, there will be a reading every five minutes. The print
format should be set to SHORT to save paper.
Because of the short thoron half life, some estimate of sample acquisition
time is needed if the thoron readings are to be properly interpreted.
During acquisition, a flow meter may be connected to the RAD7 outlet.
This will show how fast the air is flowing from the sampling point. An
estimate of the sample acquisition volume will then allow a calculation
of the time delay between sampling and measuring. Call the RAD7 one litre,
and the laboratory drying unit one litre. The soil gas probe will only
have a volume of around 50 ml, and can be ignored in comparison with
the 2 litres for the RAD7 and the drying unit. The total acquisition
delay will be 2 litres divided by the flow rate. If this is 0.5 L/min,
the delay will be 4 minutes. The thoron sensitivity stored in the RAD7
anticipates an acquisition delay of 1.4 minutes, so the extra delay in
this application will be 2.6 minutes. During that time, the thoron will
decay to 0.165 of its original concentration, so the thoron reading should
be multiplied by 6 to give the thoron concentration at the sampling point.
The final value of the thoron concentration has large uncertainties
and the absolute accuracy is probably no better than +100/-50 %.
For a soil
gas radon concentration of 200 pCi/L (8,000 Bq/m3) the 5-min radon
readings however, after the second 5-minute cycle, will be accurate
to +/-10 %
(95% confidence interval). Higher radon concentrations in the soil
will improve the accuracy of the short term readings. Averaging several
readings
will also give a more precise measurement. One disadvantage of the
thoron and sniff protocols is that the pump runs continuously, so
that much
soil gas is drawn from the sampling point. Compared with 1-day protocol,
sniff protocol will draw three times as much gas. This means that the
sphere of gas taken from the sampling point will be 1.4 times the radius
for 1-day protocol in the same total time.